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71.
采用自保护药芯焊丝明弧堆焊技术制备五组不同钨含量的Fe-Cr-C-B-W合金. 借助金相显微镜、扫描电子显微镜、X射线衍射仪、洛氏硬度计和磨损试验机分析堆焊合金的组织及性能. 结果表明,合金的显微组织由马氏体、残余奥氏体、M7(C,B)3,M3(C,B),Fe3W3C和WC组成. 大部分钨元素被迁移到晶界生成了比WC稳定性更好的Fe3W3C缺碳复合相,堆焊层中没有典型的初生WC硬质相颗粒生成. 随着钨添加量的增多,共晶硬质相M7(C,B)3,M3(C,B)和Fe3W3C随之增多,间距减小,呈连续网状均匀分布. 当钨的添加量为12%时,堆焊层的耐磨性达到最佳. 相似文献
72.
苯并噁嗪树脂作为一类新型的热固性树脂,具有分子设计性强、阻燃性能和耐腐蚀性能优异、固化时不需要强酸、无小分子放出等优点,在航空、建筑、电子等领域获得了广泛应用。本文主要介绍了苯并噁嗪单体的合成方法(溶剂法、无溶剂法和悬浮法)、降低苯并噁嗪开环聚合温度的方法(合成具有特殊基团的苯并噁嗪单体、添加催化剂)及苯并噁嗪树脂在形状记忆聚合物中的应用(与其他聚合物混合,纯苯并噁嗪化学改性),对苯并噁嗪形状记忆聚合物目前存在的问题进行了概述并对苯并噁嗪形状记忆聚合物的发展前景做出了展望。 相似文献
73.
分析了国内外露天矿山用卡车无人驾驶技术发展现状,详细介绍了露天矿山卡车无人驾驶关键技术;通过分析对比前装线控和后装线控两种技术路线的优缺点以及超声波雷达、毫米波雷达、激光雷达、4D光场智能感知系统、红外传感器、视觉传感器等环境感知技术的优缺点;提出多传感器高度融合将是露天矿山卡车实现全天候环境感知的发展方向。通过分析对比惯性导航系统、GNSS差分定位技术、车联网定位技术、电子地图定位技术、视觉传感器等定位导航技术的差异,指出多定位技术融合是露天矿山无人驾驶卡车定位方式的必然选择。结合露天煤矿的生产实际,提出将现有的无人驾驶各种技术算法与露天矿山标准作业流程有机融合是实现卡车无人驾驶的必由之路。最后指出无人驾驶卡车应用5G技术是露天矿山安全生产的关键和核心,是无人驾驶的必备技术。 相似文献
74.
Pengcheng Zhao Yu Xiang Yan Xu Yuehua Wen Wenfeng Zhang Xiayu Zhu Meng Li Zhaoqing Jin Hai Ming Gaoping Cao 《Ceramics International》2018,44(8):9105-9111
Garnet-type Li5La3Ta2O12 (LLTaO) solid electrolyte is a potential candidate component for future all-solid-state batteries due to its extraordinary stability against the reaction with molten lithium. In contrast with traditional cold isostatic pressing (CIP) method, which generally pursues ultra-high pressure, this paper tries to enhance the density and ionic conductivity of LLTaO by self-consolidation strategy without the assistance of any pressing operations. A LLTaO bulk with a relative density of 95% is obtained. SEM images reveal that the bulk sample is assembled by large dense particles in size of tens of microns indicating that the interstitial space among the particles has been dramatically minimized. Accordingly, the total ionic conductivity and the bulk ionic conductivity at 30?°C are promoted up about one order of magnitude higher to 2.63?× 10?5 S?cm?1 and 1.41?×?10?4 S?cm?1, respectively. Moreover, the lithium ionic migration network in the crystalline unit cell of LLTaO is first explored from its assembled way. A hexagon-like basic unit with tetrahedral Li1 joint sites and Li1- - Li1 edges is identified. The tetrahedral Li1 sites act as crucial junctions for the transportation of lithium ions. This work would significantly stimulate the development of LLTaO electrolyte membrane technology. 相似文献
75.
Yue Wang Jingyi Qiu Zhongbao Yu Hai Ming Meng Li Songtong Zhang Yusheng Yang 《Ceramics International》2018,44(2):1312-1320
Surface-interface reaction between the electrode and electrolyte plays a key role in lithium-ion storage properties, especially for high voltage cathode such as LiCoPO4 and Ni-riched cathode. Generally, surface modification is an effective method to improve the electrochemical performance of electrode materials. Herein, in order to revise the LiCoPO4 cathode with desirable properties, uniform AlF3-modified LiCoPO4 (LiCoPO4@AlF3) cathode materials in nano-sized distribution are synthesized. XRD result indicates that there is no structural transformation observed after AlF3 coating. TEM characterization and XPS analysis reveal that the surface of LiCoPO4 particle is coated by a nano-sized uniform AlF3 layer. Further, the electrochemical results indicate that AlF3 layer significantly improves the cycling and rate performances of LiCoPO4 cathode within the voltage range of 3.0–5.0 V. After a series of optimization, 4 mol% AlF3-coated LiCoPO4 material exhibits the best properties including an initial discharge capacity of 159 mA h g?1 at 0.1 C with 91% capacity retention after 50 cycles, especially a discharge capacity of 90 mA h g?1 can be obtained at 1 C rate. CV curves indicate that the polarization of cathode is reduced by AlF3 layer and EIS curves reveal that AlF3 layer relieves the increase of resistance to facilitate Li-ion transfer at the interface between electrode and electrolyte during the cycling process. The enhanced electrochemical performances are attributed to that the AlF3 layer can stabilize the interface between the cathode and electrolyte, form steady SEI film and suppress the electrolyte continuous decomposition at 5 V high voltages. This feasible strategy and novel characteristics of LiCoPO4@AlF3 could promise the prospective applications in the stat-art of special lithium-ion battery with high energy and/or power density. 相似文献
76.
Pengcheng Zhao Yu Xiang Yuehua Wen Meng Li Xiayu Zhu Songtong Zhao Zhaoqing Jin Hai Ming Gaoping Cao 《Journal of the European Ceramic Society》2018,38(16):5454-5462
Garnet-like Li7La3Zr2O12 electrolytes with Nb doping are synthesized by self-consolidation method. Different from conventional methods such as cold or hot isostatic pressing, not any pressing assistance is employed throughout the preparation process. Although the preparation process is dramatically simplified, both density and ionic conductivity of the obtained samples are enhanced. Nb-doped content plays a key role in the sintering of the packed precursor powders and in the structure stabilization of the obtained bulk samples. The optimized 0.60?mol Nb-doped sample with relative density of 94%, fine particle boundaries, and solitary cubic structure possesses the maximum total ionic conductivity of 5.22?×?10?4?S?cm?1 at 30?°C, which is comparable to the highest reported value of the samples prepared by conventional pressing methods. This work verifies that self-consolidation strategy is effective, reliable, and productive for the preparation of cubic Li7La3Zr2O12 electrolyte, which would significantly facilitate the development of ceramic electrolyte membrane technology. 相似文献
77.
Fei Zuo Fan Meng Dong-Tao Lin Jun-Jie Yu Hong-Jian Wang Shen Xu Wei-Ming Guo Carmen Cerecedo Víctor Valcárcel Hua-Tay Lin 《Journal of the European Ceramic Society》2018,38(4):1796-1801
A novel composite of 12 mol% CeO2-stablized tetragonal ZrO2 reinforced with Al2O3 whiskers (designated as Ce-TZP/Aw) has been prepared and studied in this work. The objective of this investigation was to systematically study the influence of whisker-aspect-ratio on the densification behaviors, microstructure evolution, and mechanical properties of Ce-TZP/Aw composite. Results showed that the sintered density of composite increased and the grain growth tended to diminish with the decrease in whisker aspect radio. Both the fracture toughness and flexural strength reached maximum values of 475 ± 12 MPa and 11.4 ± 0.2 MPa m1/2, respectively at a whisker aspect ratio of about 12. It was also observed that the fracture toughness, flexural strength and tetragonal to monoclinic ZrO2 transformation of the dual-phase composite exhibited similar variation trend as a function of the whisker-aspect-ratio, which suggested that the stress-induced phase transformation should be the main toughening and strengthening mechanism in the Ce-TZP/Aw composite. 相似文献
78.
Effect of the composition and degree of crosslinking on the properties of poly(l‐lactic acid)/crosslinked polyurethane blends 下载免费PDF全文
Meng Ma Kai Liu Haiming Zheng Si Chen Bozhen Wu Yanqin Shi Xu Wang 《Polymer International》2018,67(9):1221-1228
Poly(l ‐lactic acid)/crosslinked polyurethane (PLLA/CPU) blends which were prepared via reactive blending of PLLA with poly(?‐caprolactone) (PCL), glycerol and 4,4′‐methylenediphenyl diisocyanate showed excellent toughness. The effects of the composition of the mixture and degree of crosslinking of CPU on the toughness of the PLLA/CPU blends (80/20 w/w) were studied in detail. Dynamic mechanical analysis and rheological measurements were used to characterize the structure of the in situ formed CPU in the PLLA matrix. A novel netlike phase structure was observed when the average molecular weight of PCL and degree of crosslinking were 1 kDa and 10%, respectively. The impact strength of the blend was enhanced from 2.2 kJ m?2 for pure PLLA to 62.4 kJ m?2; meanwhile, the elongation at break was increased to 489.8%. Therefore, the mechanical properties of PLLA/CPU blends can be easily tailored by tuning the composition of the mixture and the degree of crosslinking of CPU. © 2018 Society of Chemical Industry 相似文献
79.
80.
Thermal comfort is an important factor for the design of buildings. Although it has been well recognized that many physiological parameters are linked to the state of thermal comfort or discomfort of humans, how to use physiological signal to judge the state of thermal comfort has not been well studied. In this paper, the feasibility of continuously determining feelings of personal thermal comfort was discussed by using electroencephalogram (EEG) signals in private space. In the study, 22 subjects were exposed to thermally comfortable and uncomfortably hot environments, and their EEG signals were recorded. Spectral power features of the EEG signals were extracted, and an ensemble learning method using linear discriminant analysis or support vector machine as a sub-classifier was used to build the discriminant model. The results show that an average discriminate accuracy of 87.9% can be obtained within a detection window of 60 seconds. This study indicates that it is feasible to distinguish whether a person feels comfortable or too hot in their private space by multi-channel EEG signals without interruption and suggests possibility for further applications in neuroergonomics. 相似文献